Abstract
Effective rotational molecular Hamiltonians (ERH) are constructed which differ from the traditional representation of the ERH as a power series in the total angular momentum. A Padeform of the ERH is systematically obtained and the nonuniqueness of this form is emphasized.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 8, pp. 86–90, August, 1982.
Finally, the authors thank A. V. Burenin for pointing out to us the advantages of the Pade representation of the ERH in the analysis of molecular spectra.
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Bryukhanov, V.N., Makushkin, Y.S., Tyuterev, V.G. et al. Pade form of effective rotational molecular Hamiltonians. Soviet Physics Journal 25, 756–759 (1982). https://doi.org/10.1007/BF00895256
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DOI: https://doi.org/10.1007/BF00895256