Abstract
On the basis of the use of the generalized (natural) coordinates for the description of electrons and nuclei and the representation of a molecule as a stable geometrical figure, where the electrons and nuclei interact by Coulomb’s law, while nuclei with nuclei interact elastically, a Hamiltonian describing simultaneously the electron and vibrational states and the rotations of a molecule as a whole is proposed.
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Original Russian Text © L.A. Gribov, 2016, published in Doklady Akademii Nauk, 2016, Vol. 467, No. 1, pp. 26–28.
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Gribov, L.A. A Hamiltonian for the electron-vibrational-rotational problem in the theory of molecules. Dokl. Phys. 61, 105–107 (2016). https://doi.org/10.1134/S1028335816030034
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DOI: https://doi.org/10.1134/S1028335816030034