Abstract
Experimental results are presented on the metal emission band derived from the valency band of crystals of ZrC-ZrN solid solutions, in particular the MIV, V band of Zr, in a series of intermediate zirconium carbonitrides, where the valency-electron concentration increases monotonically from 8 to 9 electrons per cell with unaltered lattice geometry and a slightly varying lattice parameter. The ZrC-TiC system represents another type of solid solution (MeIV-MeIV-X), in which the number of valency electrons remains unchanged throughout the region of continuous solid-state solubility.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 67–71, December, 1981.
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Zhurakovskii, E.A., Proskurka, K.S., Lesnaya, M.I. et al. Electronic structures and properties of carbonitride and binary carbide solutions based on titanium and zirconium. Soviet Physics Journal 24, 1127–1130 (1981). https://doi.org/10.1007/BF00893740
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DOI: https://doi.org/10.1007/BF00893740