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Instability of the crystal lattice on the verge of structural phase transitions

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Conclusion

Thus, the data of the present review lead to the conclusion that the pretransition phenomena observed on the verge of SPTs have the character of an intraphase transformation usually of the second or higher order and are observed both before low-temperature martensite transformations and in other temperature intervals. These intraphase transformations are associated with the harmonic “softening” of the crystal lattice, which may be both isotropic and anisotropic. The directions of the lattice “softening” coincide with the expected directions of its rearrangement. At the martensite transformation temperature the residual phase, too, undergoes a phase transformation, while the lattice “softening” observed during intraphase transformations increases.

The conclusions reached refer as yet to a relatively small number of alloys and are interpreted within the framework of a simple model of the crystal lattice. The problem of farther investigations is to expand the number of alloys investigated and determine how general the character of both the phenomena of intraphase transitions and of phase transformations preceding and accompanying the SPTs and the regular changes in the properties of the lattice described here are.

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Translated from Izvestiya Vysshykh Uchebnykh Zavedenii, Fizika, No. 5, pp. 118–126, May, 1985.

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Kozlov, É.V., Meisner, L.L., Klopotov, A.A. et al. Instability of the crystal lattice on the verge of structural phase transitions. Soviet Physics Journal 28, 426–432 (1985). https://doi.org/10.1007/BF00892275

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