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Infrared spectra of catalysts and adsorbed molecules communication 11. Adsorption of acetone and hydrogen on an nickel-aluminum oxide catalyst

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The adsorption of acetone and acetone with hydrogen on the surface of a mixed nickel-aluminum oxide catalyst was studied spectrally in the temperature interval 20–400°.

  2. 2.

    On the surface of the catalyst acetone forms a weakly adsorbed form, a complex with a donor-acceptor bond, a carbonate ion, and a bidentately coordinated carbonate.

  3. 3.

    Hydrogen and the complex with a donor-acceptor bond compete for the same places on the surface of the catalyst. Hydrogen promotes conversion of the donor-acceptor complex to a weakly adsorbed form.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. Ya. Denyushevskii, L. I. Lafer, V. I. Yakerson, A. M. Rubinshtein & L. A. Gorskaya

Authors
  1. V. Ya. Denyushevskii
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  2. L. I. Lafer
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  3. V. I. Yakerson
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  4. A. M. Rubinshtein
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  5. L. A. Gorskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 840–845, April, 1970.

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Denyushevskii, V.Y., Lafer, L.I., Yakerson, V.I. et al. Infrared spectra of catalysts and adsorbed molecules communication 11. Adsorption of acetone and hydrogen on an nickel-aluminum oxide catalyst. Russ Chem Bull 19, 789–793 (1970). https://doi.org/10.1007/BF00867235

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  • DOI: https://doi.org/10.1007/BF00867235

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