Skip to main content
Log in

Organosilicon and organophosphorus compounds with pseudohalide groups

3. Reactions of alkoxydimethylsilyl cyanides with tetracoordinated phosphorus halides

  • Organic Chemistry
  • Methods Of Synthesis
  • Published:
Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

The reactions of alkoxydimethylsilyl cyanides with some tetracoordinated phosphorus chlorides and fluorides were investigated. It was shown that the investigated reactions are realized primarily with the replacement of two halogen atoms by functional groups. The transformations of the phosphorus acid cyanides obtained with metal fluorides were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. A. A. Krolevets, V. V. Antipova, and I. V. Martynov, Izv. Akad. Nauk, Ser. Khim., No. 12, 2847 (1991).

  2. A. A. Krolevets and I. V. Martynov, Zh. Obshch. Khim.,61, No. 1, 259 (1991).

    Google Scholar 

  3. A. A. Krolevets, V. V. Antipova, and I. V. Martynov, Izv. Akad. Nauk, Ser. Khim., No. 7, 1593 (1991).

  4. A. A. Krolevets, V. V. Antipova, and I. V. Martynov, Izv. Akad. Nauk, Ser. Khim. (1992, in press).

  5. K. V. Karavanov, S. Z. Ivin, and V. V. Lysenko, Zh. Obshch. Khim.,35, No. 4, 737 (1965).

    Google Scholar 

  6. C. Monard and J. Quinchon, Bull. Soc. Chim. Fr.,6, 1084 (1961).

    Google Scholar 

  7. A. V. Fokin and A. A. Kolomiets, Dokl. Akad. Nauk,240, No. 5, 1131 (1978).

    Google Scholar 

  8. A. A. Krolevets, A. F. Kolomiets, A. V. Fokin, and P. V. Petrovskii, Izv. Akad. Nauk, Ser. Khim., No. 4, 897 (1980).

  9. USSR Inventor's Certificate No. 394,376; Byull. Izobret., No. 1 (1974).

  10. J. Hundeck, Z. Anorg. Allg. Chem.,345, Nos. 1–2, 23 (1966).

    Google Scholar 

  11. D. Minic, Nauc.-techn. Pregl. VTI,26, No. 2, 3 (1976).

    Google Scholar 

  12. H. L. Boter and A. J. J. Ooms, Rec. Trav. Chim.,85, No. 1, 21 (1966).

    Google Scholar 

  13. K. A. Petrov, L. G. Gatsenko, and A. A. Neimysheva, Zh. Obshch., Khim.,29, No. 6, 1827 (1959).

    Google Scholar 

  14. I. D. Shelakova, S. Z. Ivin, and V. K. Promonenkov, Methods for Obtaining Chemical Reagents and Preparations [in Russian], Vol. 20, Moscow (1969), p. 116.

    Google Scholar 

  15. A. M. Noble and J. M. Winfield, J. Chem. Soc. (A), No. 4, 501 (1970).

  16. A. Bebfington and R. V. Ley, J. Chem. Soc. (C), No. 16, 1410 (1966).

  17. V. N. Aleksandrov and V. I. Emel'yanov, Zh. Obshch. Khim.,37, No. 12, 2714 (1967).

    Google Scholar 

Download references

Authors

Additional information

For previous communication, see [1].

Institute of Physiologically Active Substances, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 187–191, January, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Krolevets, A.A., Antipova, V.V., Petrovskii, P.V. et al. Organosilicon and organophosphorus compounds with pseudohalide groups. Russ Chem Bull 41, 153–157 (1992). https://doi.org/10.1007/BF00863934

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00863934

Keywords

Navigation