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Electrochemically induced processes of formation of phosphorus acid derivatives. 4. Synthesis of trialkyl phosphates from white phosphorus

  • Physical Chemistry
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Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

The products of electrolysis in dipolar aprotic solvents on the background of tetraethylammonium iodide in the presence of white phosphorus are trialkyl phosphite (the primary product after splitting of all the P-P bonds in the phosphoric oligomers) and triaryl phosphate. It was found that the formation of triaryl phosphate from white phosphorus proceeds by way of electrochemical reduction of pentaaroxyphosphorane — an intermediate product of the reaction of triaryl phosphite with iodine and phenol. A strong dependence of the yields and distribution of the products on the composition of the electrolyte has been observed.

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Authors
  1. Yu. G. Budnikova
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  2. Yu. M. Kargin
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  3. I. M. Zaripov
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  4. A. S. Romakhin
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  5. Yu. A. Ignat'ev
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  6. E. V. Nikitin
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  7. A. P. Tomilov
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Additional information

A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 420083 Kazan'. V. I. Ul'yanov-Lenin Kazan' State University, 420008 Kazan'. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2039–2043, September, 1992.

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Budnikova, Y.G., Kargin, Y.M., Zaripov, I.M. et al. Electrochemically induced processes of formation of phosphorus acid derivatives. 4. Synthesis of trialkyl phosphates from white phosphorus. Russ Chem Bull 41, 1585–1588 (1992). https://doi.org/10.1007/BF00863577

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  • DOI: https://doi.org/10.1007/BF00863577

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