Abstract
Tris(hexafluoroisopropoxy)-bis(1-halo-2,2,2-trichloroethoxy)phosphoranes were obtained by addition of chloral to tris(hexafluoroisopropoxy)dibromo- and dichlorophosphoranes. The intermediate tris(1,1,1,3,3,3-hexafluoroisopropoxy)-1,2,2,2-tetrachloroethoxychlorophosphorane was also isolated in this reaction.
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V. I. Ul'yanov-Lenin Kazan State University, 420008 Kazan. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 683–687, March, 1992.
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Mironov, V.F., Konovalova, I.V., Ofitserov, E.N. et al. Synthesis of acyclic pentaalkoxyphosphoranes from tris(hexafluoroisopropoxy)dihalophosphoranes and chloral. Russ Chem Bull 41, 537–539 (1992). https://doi.org/10.1007/BF00863080
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DOI: https://doi.org/10.1007/BF00863080