Abstract
The theoretical strength of various ideally oriented synthetic fibers was calculated. The calculation was based on an assumption that the rupture of polymers involves simultaneous breaking of molecular chains and pulling asunder the chain ends. The temperature-time dependence of the strength of fibers was analyzed and the maximum attainable strength of fibers of various kinds was calculated to show that it is 2–5 times higher than that recorded in practice. The main causes of the difference between the attainable and attained levels of strength are associated with imperfections of the supermolecular structure and an insufficient degree of orientation of materials of this kind. The principal means of obtaining high strength levels of synthetic fibers were discussed.
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References
K. E. Perepelkin, Mekh. polim. [Polymer Mechanics], 1, 34, 1966.
V. E. Gul, Strength of Polymers [in Russian], Izd-vo Khimiya, 1964.
G. M. Bartenev and Yu. S. Zuev, Strength and Rupture of High-Elasticity Materials [in Russian], Izd-vo Khimiya, 1964.
N. V. Mikhailov and V. A. Kargin, Proceedings of the IV-th Conference on High-Molecular Compounds [in Russian], 138, 1948.
A. I. Moes et al., Transactions of the Kirov Leningrad Technical Institute [in Russian], 5, 120, 1964.
P. P. Kobeko, Amorphous Substances [in Russian], Izd-vo AN SSSR, 1952.
B. Z. Geller, ZhFKh,31, 1171, 1957.
F. J. Bueche, Appl. Phys.,28, 784, 1957.
R. Houwink, Elasticity, Plasticity and Structure of Matter, Cambridge, 1960.
De Boor, Trans. Farad. Soc.,32, 10, 1935.
H. Mark and A. V. Tobolsky, Physical Chemistry of High Polymeric System, N. Y., 1955.
H. Mark and W. Lothmar, Helv. Chim. Acta,19, 68, 1936.
S. N. Zhurkov and S. A. Abasov, Vysokomolek soed,3, 441, 450, 1961.
S. N. Zhurkov and B. N. Nårzulaev, ZhTF,23, 1677, 1953.
V. A. Kargin et al., DAN,123, 668, 1958.
S. N. Zhurkov, Z. E. Tomashevskii, and V. A. Zakrevskii, FTT,3, 2827, 1961.
G. M. Bartenev, Usp. khimii,24, 815, 1955.
T. E. Davis et al. J. Pol. Sci.,56, 485, 1962.
S. Strans and L. A. Wall, J. Res. Nat. Bur. Stand.,60, 39, 1958.
S. E. Blesler et al., Vysokomolek soed,2, 130, 1960.
R. S. Stromberg et al., J. Pol. Sci.,35, 355, 1959.
A. Hartmann, Koll.-Ztschr.,139, 146, 1954.
H. W. Starkweather, J. Pol. Sci.,21, 189, 1956.
T. Yamaguchi, Chem. High Pol. Japan,18, 405, 1961.
A. Pacault and G. Sauret, Compt. Rend. Acad. Sci.,246, 608, 1958.
E. P. Gudings, Khim. i tekhnol. polimerov,2, 104, 1961.
N. Grassi, Chemistry of Polymer Destruction Phenomena [Russian translation], IL, 1959.
S. L. Madorski et al., J. Pol. Sci.,9, 133, 1952,36, 183, 1959.
A. I. Gubanov and A. D. Chevychelov, FTT,5, 91, 2599, 1963.
B. D. Coleman et al. Text. Res. J.,28, 393, 1958.
A. I. Gubanov and A. D. Chevychelov, FTT,4, 928, 1962.
A. D. Chevychelov, FTT,5, 1394, 1963.
N. V. Mukhailov, Khim. volokna,1, 7, 1964.
M. V. Vol'kenshtein, Structure and Physical Properties of Molecules [in Russian], Izd-vo AN SSSR, 1955.
M. V. Vol'kenshtein, Configuration Statistics of Polymer Chains [in Russian], Izd-vo AN SSSR, 1959.
Z. A. Melvin-Hughes, Physical Chemistry [Russian translation], IL, 1962.
L. Pauling, The Nature of the Chemical Bond [Russian translation], Gozkhimizdat, 1947.
Ya. K. Syrkin and M. E. Dyatkina, Chemical Bonds and Molecule Structure [in Russian], Goskhimizdat, 1946.
V. N. Kondrat'ev, Structure of Atoms and Molecules [in Russian], Goskhimizdat, 1959.
S. Glesston, K. Leidler, and G. Eiring, Theory of Absolute Reaction Rates, [Russian translation], IL. 1948.
W. J. Lyons, J. Appl. Phys.,29, 1429, 1958; 30, 769, 1959.
T. Shimanouchi et al., J. Pol. Sci., 59, 93, 1962.
M. Asahina and S. Enomoto, J. Pol. Sci.,59, 101, 1962.
S. Mizushima and T. Shimanouchi, J. Amer. Chem. Soc., 71, 1320, 1949.
L. R. G. Treloar, Polymer,1, 95; 279; 290; 1960.
E. B. Wilson, J. C. Decins and R. C. Cross, Molecular Vibrations, N. Y., 1955.
G. Gerzberg, Vibration and Rotation Spectra of Multiatomic Molecules [Russian translation], IL, 1949.
R. L. Miller and L. E. Nielsen, J. Pol. Sci.,44, 391, 1960; 55, 643, 1961.
A. I. Kitaigorodskii, Organic Crystallography [in Russian], Izd-vo, AN SSSR, 1955.
R. Khuvink and A. Staverman, Chemistry and Technology of Polymers [in Russian], Izd-vo-Khimiya, 1957.
R. Hill, Synthetic Polymer Fibers, [Russian translation], IL, 1957.
P. R. Swan, J. Pol. Sci., 56, 403, 1962.
H. G. Weyband, Text. Res. J.,31, 639, 1961.
Rheology, Theory and its Applications, vol. 2 and 3, ed. R. Erich, N. Y., 1960.
T. Kawaguchi, Chem. High Pol. Japan, 18, 401, 529; 1961.
W. W. Moseley, J. Appl. Pol. Sci., 7, 187, 1963.
R. S. Laible and H. M. Morgan, J. Appl. Pol. Sci.,6, 269, 1962.
R. S. Laible and H. M. Morgan, J. Pol. Sci.,54, 53, 1961.
R. D. Wells and H. M. Morgan, Text. Res. J.,30, 668, 1960.
J. C. Smith et al. ASTM Bull., 220, 52; 1957; Text. Res. J.,31, 721, 1961.
R. Meredith, The Mechanical Properties of Textile Fibres, N.Y., 1956.
J. M. Preston, Fibre Science, Manchester, 1949.
P. Neigar, Khimiya i tekhnol. polimerov,1, 104, 1957.
A. I. Slutsker, A. E. Gromov and V. S. Pshezhetskii, FTT,6, 456, 1964.
H. Krassig, W. J. Kitchen, Pol. Sci.,51, 123, 1961; H. Krassig, Khimiya i tekhnol. polimerov, 8, 65, 1963.
A. E. Gromov and A. I. Slutsker, FTT,5, 2185, 1963.
G. N. Afanas'eva, ZhPKh,36, 1587, 1963.
C. C. Hsiao, J. Appl. Phys., 1492, 1959,30,; J. Pol. Sci., 47, 251, 1960.
T. Alfrei, Mechanical Properties of High-Molecular Polymers, [Russian translation], IL, 1952.
B. S. Sprague and H. D. Noether, Text. Res. J.,31, 858, 1961.
A. V. Stepanov, ZhETF,19, 973, 1949.
I. Sakurada et al. Chem. High Pol. Japan,21, 206, 1964.
I. Sakurada, Khimiya i tekhnol. polimerov, 10, 19, 1964.
Cellulose and Cellulose Derivates, Editors E. Ott, H. M. Spurlin, M. W. Graffin, N. Y. 1964.
A. Sippel, Kunststoffe,49, 626, 1959.
S. N. Zhurkov and S. A. Abbasov, FTT,4, 2184, 1962.
I. Sakurada, Papierfabricant,36, 252; 1958; J. Soc. Chem. Ind. Japan42, 226, 1938.
B. V. Petukhov, Doctoral dissertation, Kirov Leningrad Technical Institute, 1963.
French Patent No. 1176779. 15. 04., 1959,; See RZhKhim, no. 22, 90791 P (1960).
Chem. Week,94, 52, 1964.
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Mekhanika Polimerov, Vol. 2, no. 6, pp. 845–856, 1966
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Perepelkin, K.E. Theoretical and maximum attainable strength of various uniaxially oriented polymers (film, fibers). Polymer Mechanics 2, 536–545 (1966). https://doi.org/10.1007/BF00859975
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DOI: https://doi.org/10.1007/BF00859975