Abstract
On the assumption that the strength of linear amorphous polymers is determined by the efficiency of molecular interaction and the degree of orientation in a region adjacent to the tip of a tear, the temperature dependence of both indicated factors is described in the temperature range encompassing the rigid, high-elastic, and viscous flow states. On the basis of a comparison of the indicated temperature dependences, a σ-T curve for real polymers is proposed and confirmed by experiment. The dependence is characterized by a pronounced peak in the region of transition from the rigid state to the high-elastic state and is of exponential type in the temperature range encompassing this state.
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Mekhanika Polimerov, Vol. 1, No. 4, pp. 100–105, 1965
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Raevskii, V.G., Tolmacheva, M.N. Effect of the physical state on tearing of amorphous polymers. Polymer Mechanics 1, 56–58 (1965). https://doi.org/10.1007/BF00858895
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DOI: https://doi.org/10.1007/BF00858895