Skip to main content
SpringerLink
Log in

Dilatometric method of investigating the phase transitions of elastomers in the deformed state

  • Published:
Polymer Mechanics Aims and scope

Abstract

A method is proposed for investigating crystallization and melting processes in vulcanizates in relation to the change of volume of specimens in the compressed or extended state. The method combines the advantages of dilatometry (accuracy of quantitative estimates) and mechanical methods (possibility of acceleration of crystallization associated with orientation of the macromolecules). The vulcanizates are tested under realistic conditions. Vulcanizates of NT Nairit and cis-1,4-polybutadiene have been tested by means of the method described; the crystallization kinetics are shown to depend on the degree of extension and compression of the specimens.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. F. Bukhina, Dissertation, Moscow (1963).

  2. A. I. Marei, G. P. Petrova, G. E. Novikova, and S. K. Kurlyand, Proc. 17-th Conf. on High-Molec. Compounds [in Russian], Moscow (1969).

  3. A. I. Marei and G. P. Petrova, Proc. 5-th Conf. on the Substitution of Synthetic for Natural Rubber [in Russian], Yaroslavl' (1964).

  4. A. I. Marei, N. P. Kuznetsov, and G. E. Novikova, Kauchuk i Rezina, No. 3, 41 (1965).

  5. G. Gee, I. Stern, and L. R. G. Treloar, Trans. Farad. Soc.,46, No. 12, 1101 (1950).

    Google Scholar 

  6. A. N. Gent, Trans. Farad. Soc.,50, No. 5, 521 (1954).

    Google Scholar 

Download references

Authors
  1. A. I. Marei
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. K. Grigor'yants
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. E. Novikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. P. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. K. Kurlyand
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. N. Rumyantsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. F. Galkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Lebedev All-Union Scientific-Research Institute of Synthetic Rubber, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 780–784, September–October, 1970.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Marei, A.I., Grigor'yants, I.K., Novikova, G.E. et al. Dilatometric method of investigating the phase transitions of elastomers in the deformed state. Polymer Mechanics 6, 678–681 (1970). https://doi.org/10.1007/BF00856195

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00856195

Keywords

Search

Navigation