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Investigation of certain adducts of boron trifluoride with trialkyl(aryl)phosphines

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Fluoro derivatives of boraphosphanes were produced by the reaction of trialkyl(phenyl)phosphines with boron trifluoride etherate.

  2. 2.

    The IR spectra of the synthesized products were taken, and a coordination structure was confirmed.

  3. 3.

    Decomposition of the products begins in the interval 180–200° in air and 200–220° in an atmosphere of nitrogen.

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Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    Vikt I. Spitsyn, I. D. Kolli, E. M. Sadykova & R. G. Nesterenko

Authors
  1. Vikt I. Spitsyn
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  2. I. D. Kolli
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  3. E. M. Sadykova
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  4. R. G. Nesterenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 45–50, January, 1972.

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Spitsyn, V.I., Kolli, I.D., Sadykova, E.M. et al. Investigation of certain adducts of boron trifluoride with trialkyl(aryl)phosphines. Russ Chem Bull 21, 39–42 (1972). https://doi.org/10.1007/BF00855652

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  • DOI: https://doi.org/10.1007/BF00855652

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