Abstract
The effect of the chemical structure of the plasticizer on the autohesive strength of elastomer systems has been investigated with reference to P-200 and SKN-40 elastomers containing a series of sebacates and phthalates. Increasing the length of the hydrocarbon radical of the plasticizer molecule increases the autohesion of nonpolar P-200 and reduces that of polar SKN-40. The data confirm the existence of different plasticization mechanisms in nonpolar and polar elastomers and are consistent with a diffusion autohesion model.
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Yu. S. Maloshuk, V. G. Raevskii, A. A. Semenikhina, and S. S. Voyutskii, Mekh. polim. [Polymer Mechanics], 2, 15, 1965.
Yu. S. Maloshuk, V. G. Raevskii, A. A. Semenikhina, and S. S. Voyutskii, Mekh. polim. [Polymer Mechanics], 3, 77, 1965.
Yu. S. Maloshuk, A. T. Titarenko, V. G. Raevskii, and S. S. Voyutskii, Mekh. polim. [Polymer Mechanics], 6, 857, 1966.
N. P. Priklonskaya, Kauchuk i rezina, 5, 49, 1937.
G. N. Buiko, N. M. Arenzon, A. I. Tumanova, N. P. Zinchenko, N. A. Pruzhanskaya, E. A. Pakhomova, A. I. Kolomytseva, and E. G. Bugrova, in: Bond Strength Between the Elements of Rubber-Fabric Multi-Ply Articles in Production and Service [in Russian], Goskhimizdat, 29, 1956.
S. S. Voyutskii, Autohesion and Adhesion of High Polymers [in Russian], Rostekhizdat, 1960.
P. V. Kozlov, ZhVKhO, 9, 660, 1964.
V. A. Voskresenskii and E. M. Orlova, Usp. khim.,33, 320, 1964.
A. G. Belorossova, M. I. Farberov, and V. G. Epshtein, in: Bond Strength Between the Elements of Rubber-Fabric Multi-Ply Articles in Production and Service [in Russian], Goskhimizdat, 131, 1956.
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Mekhanika Polimerov, Vol. 4, No. 2, pp. 296–299, 1968
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Maloshuk, Y.S., Titarenko, S.A., Raevskii, V.G. et al. Autohesion of commercial elastomer systems. Polymer Mechanics 4, 233–236 (1968). https://doi.org/10.1007/BF00855625
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DOI: https://doi.org/10.1007/BF00855625