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Increasing the adhesion of polymers to metals by adding substances with conjugation systems

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Polymer Mechanics Aims and scope

Abstract

The electron-donor properties of polymers with conjugation systems (PCS) and their capability of forming π-complexes with metals is of interest in relation to adhesion. Small amounts (0.01–0.1%) of substances with polyconjugation systems (polydiphenylbutadiene, polyphenylacetylene, and copolymers of naphthalene and anthracene with benzene) increase the adhesion between aluminum and polymers used as electrical insulation coatings (polyesters, polyimides, and their derivatives). With optimum PCS dosage, the resistance to peeling rises by 15–38%.

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Authors
  1. A. A. Berlin
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  2. V. E. Basin
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  3. M. I. Cherkashin
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  4. M. G. Chauser
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  5. V. A. Grigorovskaya
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Additional information

Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 2, pp. 365–367, March–April, 1974.

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Berlin, A.A., Basin, V.E., Cherkashin, M.I. et al. Increasing the adhesion of polymers to metals by adding substances with conjugation systems. Polymer Mechanics 9, 326–328 (1973). https://doi.org/10.1007/BF00855063

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  • DOI: https://doi.org/10.1007/BF00855063

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