Skip to main content
Log in

Thermodynamic equilibrium of a gas mixture with a solution in the condensed phase

  • Published:
Journal of Engineering Physics and Thermophysics Aims and scope

Abstract

A thermodynamic analysis is made of the equilibrium of a gas mixture (using a nitrogen-hydrogen mixture as an example) with a solid solution of its components. The processes occurring in the surface layer and interphase exchange are taken into account. The equilibrium characteristics are determined in terms of the equilibrium constants of the intermediate stages of the surface reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature Cited

  1. Yu. A. Buevich, Khim. Fiz.,6, No. 10, 1436 (1987).

    Google Scholar 

  2. A. I. Rusanov, Phase Equilibrium and Surface Phenomena [in Russian], Leningrad (1967).

  3. S. L. Kiperman, Introduction to the Kinetics of Heterogeneous Catalytic Reactions [in Russian], Moscow (1964).

  4. N. K. Bulatov and A. B. Lundin, Thermodynamics of Irreversible Physicochemical Processes [in Russian], Moscow (1984).

  5. I. Prigogine and R. Defay, Chemical Thermodynamics, Wiley, New York (1954).

    Google Scholar 

  6. R. Fowler and E. Gugenheim, Statistical Thermodynamics [Russian translation], Moscow (1949).

  7. M. N. Leonidova, L. A. Shvartsman, and L. A. Shul'ts, Physicochemical Fundamentals of the Reaction of Metals with Controlled Atmospheres [in Russian], Moscow (1980).

Download references

Authors

Additional information

A. M. Gorkii Ural State University. S. M. Kirov Ural Polytechnical Institute, Ekaterinburg. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 62, No. 4, pp. 624–628, April, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kamennykh, A.V., Yasnikov, G.P. Thermodynamic equilibrium of a gas mixture with a solution in the condensed phase. J Eng Phys Thermophys 62, 460–464 (1992). https://doi.org/10.1007/BF00854964

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854964

Keywords

Navigation