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Investigation of the three-dimensional structure of a quinone oxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

On the basis of the measurement of the dipole moment and molar Kerr constant it was shown that the quinone oxide molecule exists in the form of a boat with syn-orientation of the oxide ring, stabilized by conjugation of the carbonyl groups with the three-membered ring and by the energies of orientation of the bonds.

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Literature cited

  1. A. N. Vereshchagin and S. G. Vul'fson, Zh. Tekh. Fiz.,9, 1090 (1968).

    Google Scholar 

  2. A. N. Vereshchagin, A. P. Anastas'eva, and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 559 (1969).

  3. V. A. Naumov and V. M. Bezzubov, Zh. Tekh. Fiz.,8, 530 (1967).

    Google Scholar 

  4. B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 2377 (1969).

  5. A. Rashid and G. Read, J. Chem. Soc., C, 2053 (1969).

    Google Scholar 

  6. C. Djerassi, W. Klyne, T. Norin, G. Ohloff, and E. Klein, Tetrahedron,21, 163 (1965).

    Google Scholar 

  7. D. F. O'Brien and J. W. Gates, J. Organ. Chem.,30, 2593 (1965).

    Google Scholar 

  8. R. J. W. Le Fevre, Advances in Physical Organic Chemistry, V. Gold (editor), New York-London (1965), p. 3.

  9. R. J. W. Le Fevre, B. J. Orr, and G. L. Ritchie, J. Chem. Soc., B, 273 (1966).

    Google Scholar 

  10. L. A. Gribov and E. M. Popov, Dokl. Akad. Nauk SSSR,145, 761 (1962).

    Google Scholar 

  11. H. G. Horment, Acta Crystallogr.,18, 627 (1965).

    Google Scholar 

  12. T. L. Hill, J. Chem. Phys.,16, 399 (1948).

    Google Scholar 

  13. W. Kozman, Introduction to Quantum Chemistry [Russian translation], IL (1960), p. 384.

  14. L. Meyer, Z. Phys. Chem.,8, 27 (1930).

    Google Scholar 

  15. E. Streitwiser, The Theory of Molecular Orbitals [Russian translation], Mir (1965), p. 113.

  16. T. I. Temnikova, Course in the Theoretical Bases of Organic Chemistry [in Russian], Goskhimizdat (1962), p. 481.

  17. D. Roberts, Calculations According to the Molecular Orbital Method [Russian translation], IL (1963), p. 53.

  18. N. P. Borisova and M. V. Vol'kenshtein, Zh. Struk. Khim.,2, 469 (1961).

    Google Scholar 

  19. K. Alder, F. A. Flock, and H. Beumling, Ber.,93, 1896 (1960).

    Google Scholar 

  20. E. Guggenheim and J. Pru, Physicochemical Calculations [Russian translation], IL (1958), p. 100.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson & A. A. Solov'ev

Authors
  1. B. A. Arbuzov
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  2. A. N. Vereshchagin
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  3. S. G. Vul'fson
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  4. A. A. Solov'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1291–1294, June, 1972.

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Arbuzov, B.A., Vereshchagin, A.N., Vul'fson, S.G. et al. Investigation of the three-dimensional structure of a quinone oxide. Russ Chem Bull 21, 1246–1248 (1972). https://doi.org/10.1007/BF00854537

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  • DOI: https://doi.org/10.1007/BF00854537

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