Skip to main content
SpringerLink
Log in

Study of the autoassociation in hydrazines by the NMR method

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The model of associations monomer ⇌ cyclic dimer, proposed earlier for dimethylhydrazines (DMH), is incorrect.

  2. 2.

    Association occurs according to the scheme monomer ⇌ cyclic n-mer with n=3 for 1,1-DMH and n=3 and 4 for 1,2-DMH.

  3. 3.

    The association constants were determined for a number of temperatures, enthalpies and entropies of formation of associates, as well as average values of the hydrogen bond energy for the models considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. Saunders and J. B. Hyne, J. Chem. Phys.,29, 1319 (1958).

    Google Scholar 

  2. J. R. Crook and K. Schug, J. Amer. Chem. Soc.,86, 4271 (1964).

    Google Scholar 

  3. J. Amesley, J. Finney, and L. Sutcliff, High Resolution NMR Spectroscopy [Russian translation], Mir (1968), p. 1.

  4. J. Biais, B. Lemanceau, and C. Lussan, J. Chim. Phys. et Phys. Chim. Biol.,64, 1019, 1030 (1967).

    Google Scholar 

  5. L. N. Erofeev and A. A. Kirnov, USSR Patent No. 265545, June 22, 1968; Byul. Izobr. No. 10, 130 (1970).

  6. N. Muller and R. S. Reiter, J. Chem. Phys.,42, 3265 (1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    N. G. Yunda, G. V. Lagodzinskaya & G. B. Manelis

Authors
  1. N. G. Yunda
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. V. Lagodzinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. B. Manelis
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1284–1287, June, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yunda, N.G., Lagodzinskaya, G.V. & Manelis, G.B. Study of the autoassociation in hydrazines by the NMR method. Russ Chem Bull 21, 1240–1242 (1972). https://doi.org/10.1007/BF00854535

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854535

Keywords

Search

Navigation