Skip to main content
Log in

Some principles of the radiolysis of crystalline inorganic compounds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The value of the electron affinity can serve as one of the criteria determining the course of primary products of radiolysis of inorganic salts.

  2. 2.

    With increasing electron affinity of the anion in series of monotypic oxygen-containing salts, the yield of primary radiolysis products formed as a result of ionization is reduced.

  3. 3.

    The influence of anionic impurities on radiolysis depends on the ratio of the electron affinity of the impurity and that of the anion of the matrix.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. Yu. A. Zakharov and V. A. Nevostruev, Uspekhi Khimii,37, 43 (1968).

    Google Scholar 

  2. O. Constantinescu, I. Pascaru, and M. Constantinescu, Rev. Roum. Physic.,10, 7 (1965);11, 3 (1966);12, 1 (1967).

    Google Scholar 

  3. V. V. Gromov, Dissertation [in Russian], Moscow (1969).

  4. A. Raymond, Thesis Ph. D., Inst. Techn., Chicago, Illinois (1967).

    Google Scholar 

  5. A. A. Prince and E. R. Johnson, J. Phys. Chem.,69, 359, 377 (1965).

    Google Scholar 

  6. H. G. Heal, Canad. J. Chem.,31, 91 (1953).

    Google Scholar 

  7. G. Boyd, E. W. Graham, and R. W. Larson, J. Phys. Chem.,66, 300 (1962).

    Google Scholar 

  8. J. Cunningham, J. Phys. Chem.,65, 628 (1961);66, 779 (1962).

    Google Scholar 

  9. S. R. Huang, Thesis Ph. D., Stevans Inst. Techn., Hoboken, N. J. (1964).

    Google Scholar 

  10. S. Ya. Pshezhetskii, Mechanisms of Radiation Chemical Reactions [in Russian], Khimiya (1968), Chap. 9.

  11. L. G. Karaseva, Dissertation [in Russian], Moscow (1969).

  12. V. I. Spitsyn, B. G. Ershov, L. I. Barsova, and G. Yu. Popova, Izv. Akad. Nauk SSSR, Ser. Khim., 1961 (1970); Dokl. Akad. Nauk SSSR,197, 1355 (1971).

  13. V. I. Vedenev, L. V. Gurvich, V. N. Kondrat'ev, V. A. Medvedev, and E. L. Frankevich, Cleavage Energies of Chemical Bonds, Ionization Potentials and Electron Affinity, Handbook [in Russian], Izd-vo AN SSSR (1962).

  14. V. V. Boldyrev and L. I. Bystrykh, Uspekhi Khimii,32, 948 (1963).

    Google Scholar 

  15. C. Coulson, Valency [Russian translation], Mir (1965), Chap. I.

  16. A. A. Vorob'ev, Izv. Akad. Nauk SSSR, Ser. Fiz.,29, 361 (1965); Usp. Khim.,36, 1065 (1967); Izv. Vuzov. Fizika,8, 159 (1967);10, 39 (1967).

    Google Scholar 

  17. L. I. Barsova, B. G. Ershov, G. Yu. Popova, and Vikt. I. Spitsyn, Dokl. Akad. Nauk SSSR,184, 1124 (1964).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimecheskaya, No. 4, pp. 796–801, April, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Medvedev, A.S., Gromov, V.V. Some principles of the radiolysis of crystalline inorganic compounds. Russ Chem Bull 21, 755–759 (1972). https://doi.org/10.1007/BF00854467

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854467

Keywords

Navigation