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A high-temperature mass-spectrometric method for determination of the electron work function of ionic crystals: Lanthanum, cerium, and praseodymium triiodides

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

A mass spectrometric method for the determination of the electron work function based on analysis of thermochemical cycles including molecules and ions has been described. Application of this method for calculation of the electron work functions of lanthanum, cerium, and praseodymium triiodides gave 3.8±0.3 eV for LaI3, 3.5±0.3 eV for CeI3, and 2.8±0.3 eV for PrI3.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology (ISUCT), pr. Sheremetevskii 7, Ivanovo, 153000, Russia

    A. M. Dunaev, V. B. Motalov & L. S. Kudin

Authors
  1. A. M. Dunaev
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  2. V. B. Motalov
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  3. L. S. Kudin
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Correspondence to A. M. Dunaev.

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Original Russian Text © A.M. Dunaev, V.B. Motalov, L.S. Kudin, 2015, published in Rossiiskii Khimicheskii Zhurnal, 2015, Vol. 59, Nos. 1–2, pp. 87–93.

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Dunaev, A.M., Motalov, V.B. & Kudin, L.S. A high-temperature mass-spectrometric method for determination of the electron work function of ionic crystals: Lanthanum, cerium, and praseodymium triiodides. Russ J Gen Chem 87, 632–638 (2017). https://doi.org/10.1134/S1070363217030410

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