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Synthesis of 3-carbethoxybicyclo[2.1.0]-2-pentanone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In contrast to the diethyl ester of adipic acid, the diethyl ester of cis-dihydromuconic acid is not cyclized under the conditions of the Dieckmann reaction.

  2. 2.

    2-Carbethoxybicyclo[2.1.0]-2-pentanone is smoothly formed by the dehydrobromination of 2-bromo-2-carbethoxy-1-cyclopentanone with BF3 etherate.

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Author information

Authors and Affiliations

  1. M. M. Shemyakin Institute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR, USSR

    N. K. Levchenko, G. M. Segal & I. V. Torgov

Authors
  1. N. K. Levchenko
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  2. G. M. Segal
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  3. I. V. Torgov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1086–1090, May, 1973.

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Levchenko, N.K., Segal, G.M. & Torgov, I.V. Synthesis of 3-carbethoxybicyclo[2.1.0]-2-pentanone. Russ Chem Bull 22, 1042–1046 (1973). https://doi.org/10.1007/BF00854246

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  • DOI: https://doi.org/10.1007/BF00854246

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