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Investigation of the interaction in the systems C2H2-HCl and C2H2-Cl2 at low temperatures by the method of IR spectroscopy

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The existence of donor-acceptor-type molecular complexes in the systems C2H2-HCl and C2H2-Cl2 was detected by the method of IR spectroscopy in the solid phase at temperatures close to the temperature of liquid nitrogen.

  2. 2.

    At low temperatures (~ 95°K), under conditions of good mixing of the components, there is a reaction of selective addition of acetylene at the multiple bond, with the formation of trans-1, 2-dichloroethylene.

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Authors and Affiliations

  1. Institute of Spectroscopy, Academy of Sciences of the USSR, USSR

    Ya. M. Kimel'feld, É. V. Lumer & A. P. Shvedchikov

  2. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    Ya. M. Kimel'feld, É. V. Lumer & A. P. Shvedchikov

Authors
  1. Ya. M. Kimel'feld
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  2. É. V. Lumer
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  3. A. P. Shvedchikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 979–982, May, 1973.

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Kimel'feld, Y.M., Lumer, É.V. & Shvedchikov, A.P. Investigation of the interaction in the systems C2H2-HCl and C2H2-Cl2 at low temperatures by the method of IR spectroscopy. Russ Chem Bull 22, 944–946 (1973). https://doi.org/10.1007/BF00854228

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  • DOI: https://doi.org/10.1007/BF00854228

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