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Bromination of 2-halo- and 2,2-dihaloadamantanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the behavior of the 2,2-dibromo-, 2,2-dichloro-, and 2-chloroadamantanes in the presence of AlBr3, both in organic solvents and in bromine medium.

  2. 2.

    The synthesis of the tri- and tetrabromoadamantanes from the 2-chloro- and 2,2-dichloroadaman-tanes is accomplished under milder conditions than from the nodal mono- and dibromoadamantanes.

  3. 3.

    The dibromoadamantanes that are formed during the bromination of the 2,2-di- and 2-chloroadamantanes contain predominantly the diaxial 2,4-dibromoadamantane, while 1,3,6-tribromoadamantane is the principal component in the tribromoadamantanes.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    L. S. Simonenko, A. M. Kotlyarov & S. S. Novikov

Authors
  1. L. S. Simonenko
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  2. A. M. Kotlyarov
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  3. S. S. Novikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 49–53, January, 1973.

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Simonenko, L.S., Kotlyarov, A.M. & Novikov, S.S. Bromination of 2-halo- and 2,2-dihaloadamantanes. Russ Chem Bull 22, 44–47 (1973). https://doi.org/10.1007/BF00854111

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  • DOI: https://doi.org/10.1007/BF00854111

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