Abstract
Catalytic chlorination and bromination of diamantane with halomethanes was performed under the action of zeolites NaY-mmm, HY-mmm, and FeHY-mmm. Optimal ratios of the catalyst, reagents and conditions for selective synthesis of chloro- and bromo-substituted diamantanes were found.
Similar content being viewed by others
References
Bagrii, E.I., Adamantany (Adamantanes), Moscow: Nauka, 1989, p. 264.
Schwertfeger, H., Fokin, A.A., and Schreiner, P.R., Angew. Chem. Int. Ed., 2008. 47, p. 1022. doi 10.1002/anie.200701684
Courtney, T., Johnston, D.E., McKervey, M.A., Rooney, J.J., J. Chem. Soc., 1972, vol. 1, p. 2691. doi 10.1039/P197200FP003
Khusnutdinov, R.I., Shchadneva, N.A., and Dzhemilev, U.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1991, no. 12, p. 2897. doi 10.1007/BF00959743
RF Patent 2125552, 1999.
Khusnutdinov, R.I., Shchadneva, N.A., Baiguzina, A.R., Lavrent’eva, Yu.Yu., Burangulova, R.Yu., and Dzhemilev, U.M., Petroleum Chem., 2004, vol. 44, no. 2, p. 126.
Gund, T.M., Schleyer, P.R., Unruh, G.D., and Gleicher, G.J., J. Org. Chem., 1974, vol. 39, p. 2995. doi 10.1021/jo00934a011
Fokin, A.A., Tkachenko, B.A., Gunchenko, P.A., Gusev, D.V., and Schreiner, P.R., Chem. Eur. J., 2005, vol. 11, p. 7091. doi 10.1002/chem.200500031
Krishnamurthy, V.V., Shih, J.G., and Olah, G.A., J. Org. Chem., 1985, vol. 50, no. 8, p. 1161. doi 10.1021/jo00208a003
Khusnutdinov, R.I., Shchadneva, N.A., and Khisamova, L.F., Russ. J. Org. Chem., 2017, vol. 53, no. 2, p. 163. doi 10.1134/S1070428015020074
Kutepov, B.I., Travkina, O.S., Pavlova, I.N., Khazipova, A.N., Grigor’eva, N.G., and Pavlov, M.L., Russ. J. Appl. Chem., 2015, vol. 88, no. 1, p. 65. doi 10.1134/S1070427215010103
Ola, G., Schilling, P., Renner, R., and Kerekes, J., J. Org. Chem., 1974, vol. 39, p. 3472. doi 10.1021/jo00938a003
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © R.I. Khusnutdinov, N.A. Shchadneva, Yu.Yu. Mayakova, A.A. Yulamanova, A.N. Khazipova, B.I. Kutepov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 5, pp. 724–728.
Rights and permissions
About this article
Cite this article
Khusnutdinov, R.I., Shchadneva, N.A., Mayakova, Y.Y. et al. Halogenation of Diamantane by Halomethanes Under the Action of Zeolites. Russ J Gen Chem 88, 869–873 (2018). https://doi.org/10.1134/S1070363218050043
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363218050043