Conclusions
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1.
Under the conditions of reduction studies, a substantial amount of the NiO phase remains in Ni-Cr2O3 catalysts, and does not disappear even during the dehydrogenation of cyclohexane on these catalysts. During the work there is an appreciable increase in the dimensions of the Ni crystals.
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2.
In coprecipitated oxides with the composition NiO-CuO-Cr2O3, at the temperature of calcination 600°, intensive formation of spinel NiCr2O4 is observed.
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3.
Reduced Ni-Cu-Cr2O3 catalysts contain a substantial amount of the NiO phase, the NiCr2O4 phase, and the Ni-Cu solid solution, and metallic nickel as well in the case of a larger nickel content.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 691–697, April, 1971.
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Rubinshtein, A.M., Slinkin, A.A., Klyachko-Gurvich, A.L. et al. The structure and activity of Ni-Cr2O3 and Ni-Cu-Cr2O3 catalysts. Russ Chem Bull 20, 621–625 (1971). https://doi.org/10.1007/BF00853886
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DOI: https://doi.org/10.1007/BF00853886