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Reaction of chlorophosphines withβ-chloroacrylic acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reactions of methyl-, ethyl-, and phenyldichlorophosphine with cis-β-chloroacrylic acid lead to the formation of the acid chlorides of methyl-, ethyl-, and phenyl-(β-chloroformylvinyl)phosphinic acid.

  2. 2.

    With trans-β-chloroacrylic acid the reaction proceeds with the formation of the acid chloride of trans-β-chloroacrylic acid.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    A. N. Pudovik, G. V. Dmitrieva, N. P. Anoshina, T. A. Zyablikova & V. K. Khairullin

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  1. A. N. Pudovik
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  2. G. V. Dmitrieva
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  3. N. P. Anoshina
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  4. T. A. Zyablikova
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  5. V. K. Khairullin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1159–1164, May, 1972.

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Pudovik, A.N., Dmitrieva, G.V., Anoshina, N.P. et al. Reaction of chlorophosphines withβ-chloroacrylic acid. Russ Chem Bull 21, 1109–1113 (1972). https://doi.org/10.1007/BF00853780

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  • DOI: https://doi.org/10.1007/BF00853780

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