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Synthesis of binuclear complexes of transition metals

Communication 4. Synthesis of σ,π-binuclear complex from σ-styryl- and σ-cinnamoyl-π-cyclopentadienyliron dicarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the effect of steric and electronic factors on the possibility of forming σ,π-binuclear complexes of iron.

  2. 2.

    A method was developed for the synthesis of the previously unknown compound, σ-styryl-π-cyclopentadienyliron dicarbonyl, and a new σ,π-binuclear complex was obtained from it.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, L. V. Rybin, M. I. Rybinskaya, V. S. Kaganovich & P. V. Petrovskii

Authors
  1. A. N. Nesmeyanov
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  2. L. V. Rybin
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  3. M. I. Rybinskaya
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  4. V. S. Kaganovich
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  5. P. V. Petrovskii
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Additional information

See [8] for Communication 3.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2733–2738, December, 1971.

The authors express their gratitude to B. V. Lokshin for assistance in taking and interpreting the IR spectra.

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Nesmeyanov, A.N., Rybin, L.V., Rybinskaya, M.I. et al. Synthesis of binuclear complexes of transition metals. Russ Chem Bull 20, 2592–2596 (1971). https://doi.org/10.1007/BF00853630

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  • DOI: https://doi.org/10.1007/BF00853630

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