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Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand

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Abstract

In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.

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Acknowledgements

This work was financially supported by the Serbian Ministry of Education, Science and Technological Development (Grant No. 172035, 172017). D.M.S wishes to thank the Magbiovin project (FP7-ERAChairs-Pilot Call-2013, Grant agreement: 621375).

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Authors and Affiliations

  1. Vinča Institute of Nuclear Sciences, University of Belgrade, Mike Petrovića Alasa 12-14, 11001, Belgrade, Serbia

    Marko Perić & Dalibor M. Stanković

  2. Joseph Banks Laboratories, School of Chemistry, University of Lincoln, Lincoln, LN6 7DL, UK

    Sara H. Kyne

  3. Faculty of Chemistry, University of Belgrade, Studentski Trg 12-16, 11001, Belgrade, Serbia

    Maja Gruden & Ilija Brčeski

  4. Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 3, 21000, Novi Sad, Serbia

    Marko Rodić

  5. Innovation Center of the Faculty of Chemistry, University of Belgrade, Studentski Trg 12–16, 11001, Belgrade, Serbia

    Dejan Jeremić & Dalibor M. Stanković

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  1. Marko Perić
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Perić, M., Kyne, S.H., Gruden, M. et al. Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. Monatsh Chem 150, 1241–1248 (2019). https://doi.org/10.1007/s00706-019-02405-7

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