Conclusions
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1.
Organosilicon oligomers with an ordered structure were obtained from (chlorophenylethyl)methyldichlorosilane and 3,4-benzo-1,1-dichloro-1-silacyclohexane by the double decomposition reaction with disodium salts, followed by closure of the chain employing a triorganochlorosilane.
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2.
We made a study of the dependence of the viscosity on the temperature for the synthesized compounds, and we also determined the freezing points and calculated the activation energies of viscous flow.
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Literature cited
M. A. Kleinovskaya, M. V. Sobolevskii, T. A. Krasovskaya, and N. M. Zharkova, Plast. Massy, No. 9, 19 (1962).
K. A. Andrianov, T. N. Ganina, N. N. Sokolov, and E. N. Khrustaleva, Zh. Obshch. Khim.,30, 2777 (1960).
K. A. Andrianov and Shu-Meng Sung, Vysokomolekul. Soedin.,2, 554 (1960); Chem. Abstrs.,50, 5011a (1961).
D. Ya. Zhinkin, Plast. Massy, No. 2, 37 (1959).
K. A. Andrianov and V. V. Severnyi, Dokl. Akad. Nauk SSSR,134, 1347 (1960).
K. A. Andrianov, V. V. Severnyi, and B. G. Zavin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1458 (1961).
K. A. Andrianov, V. V. Severnyi, and B. G. Zavin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1615 (1961).
K. A. Andrianov and A. I. Petrashko, Vysokomolekul. Soedin.,10, 1514 (1959).
K. A. Andrianov and A. A. Zhdanov, Dokl. Akad. Nauk SSSR,114, 1005 (1957).
F. H. Hyde, US Patent No. 2567110; Chem. Abstrs.,45, 10676 (1951).
M. V. Sobolevskii, L. A. Chistyakova, and D. V. Nazarova, Plast. Massy, No. 10, 17 (1962).
Ural Branch of the Academy of Sciences, Transactions of the Institute of Chemistry. Heteroorganic Compounds [in Russian], No. 13 (1966), p. 25.
K. A. Andrianov, A. A. Zhdanov, and V. A. Odinets, Zh. Obshch. Khim.,31, 4033 (1961).
A. A. Zhdanov, K. A. Andrianov, V. A. Odinets, and I. V. Karpova, Zh. Obshch. Khim.,36, 521 (1966).
M. V. Sobolevskii, L. A. Chistyakova, V. V. Kirilina, and D. V. Nazarova, USSR Patent No. 141156, (August 25, 1961); Byull. Izobr., No. 18, 17 (1961).
W. A. Daudt and J. F. Hyde, J. Am. Chem. Soc.,74, 386 (1952).
K. A. Andrianov, A. A. Zhdanov, I. V. Karpova, and V. A. Odinets, Izv. Akad. Nauk SSSR, Ser. Khim., 2733 (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2238–2242, October, 1971.
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Andrianov, K.A., Zhdanov, A.A., Odinets, V.A. et al. Synthesis and study of properties of someα,ω-hexaorganopolydiorganosiloxanes. Russ Chem Bull 20, 2114–2117 (1971). https://doi.org/10.1007/BF00851261
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DOI: https://doi.org/10.1007/BF00851261