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Chemistry of glycosyl phosphates and their derivatives

COmmunication 2. Synthesis of desoxyglycosyl phosphates, derivatives of 6-, 4-, and 3-desoxy-d-glucose

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The fusion of theβ-tetraacetates of desoxy sugars with H3PO4 was used to obtain the 6, 4, and 3-desoxyglycosyl phosphates.

  2. 2.

    The optimum conditions for the separation of theα- andβ-anomers of the desoxyglycosyl phosphates were selected.

  3. 3.

    The previously unknown 2,3,6-tri-O-benzoyl-4-desoxy-α-methyl-D-xylo-hexopyranoside was obtained.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. N. Shibaev, Yu. Yu. Kusov, Sh. Kuchar & N. K. Kochetkov

Authors
  1. V. N. Shibaev
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  2. Yu. Yu. Kusov
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  3. Sh. Kuchar
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  4. N. K. Kochetkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp.430–434, February, 1973.

Sh. Kuchar is a co-worker at the Institute of Chemistry of the Slovakia Academy of Sciences.

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Shibaev, V.N., Kusov, Y.Y., Kuchar, S. et al. Chemistry of glycosyl phosphates and their derivatives. Russ Chem Bull 22, 408–412 (1973). https://doi.org/10.1007/BF00851002

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  • DOI: https://doi.org/10.1007/BF00851002

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