Conclusions
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1.
The basic chlorine-containing reaction products of antimony pentafluoride with Cl2O and ClO2 are chloryl fluoroantimonates and chlorine; the basic chlorine-containing products of the reactions of SbF5 with Cl2O6 are chloryl fluoroantimonates and perchloryl fluoride.
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2.
Chlorine monoxide and dioxide react with antimony pentafluoride, contained in the polymer ion Sb3F −16 , with the formation of the same products as with free SbF5.
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3.
As a result of the interaction of Cl2O7 and SbF5, perchloryl fluoride and unidentified oxyfluorides of antimony, containing an admixture of the chloryl salt, are formed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp.273–279, February, 1973.