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A study of the reaction between an aluminum alkyl and an acyl peroxide

Communication 2. The nature of the free radicals formed during the reaction of aluminum alkyls with benzoyl peroxide
  • L. V. Zamoiskaya
  • E. B. Milovskaya
  • V. A. Orestova
Organic and Biological Chemistry
  • 25 Downloads

Conclusions

  1. 1.

    The reaction between the aluminum alkyls (AlEt3 and Al(i-C4H9)3) and benzoyl peroxide has been studied both in the presence and absence of free radical acceptors.

     
  2. 2.

    The reaction between an aluminum alkyl and a peroxide is accompanied only by the formation of alkyl free radicals. The organoaluminum compound and not the peroxide is the direct source of these radicals.

     

Keywords

Aluminum Peroxide Free Radical Benzoyl Benzoyl Peroxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • L. V. Zamoiskaya
    • 1
  • E. B. Milovskaya
    • 1
  • V. A. Orestova
    • 1
  1. 1.Institute of High Molecular Weight CompoundsAcademy of Sciences of the USSRUSSR

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