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Organoboron compounds

Communication 209. The cleavage of the boron-carbon bond in 2-alkoxy-1,4-pentadienyl compounds of boron under the action of alcohols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of 2-alkoxyvinyl compounds of boron with alcohols was studied.

  2. 2.

    The boron-carbon bond in trans-2-alkoxyvinyl compounds of boron is cleaved considerably more readily by alcohols than the B-alkyl bond, which is explained by the greater polarity of the B-Csp 2 bond in comparison with the B-Csp 3 bond.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    Yu. N. Bubnov, S. A. Korobeinikova, G. V. Isagulyants & B. M. Mikhailov

Authors
  1. Yu. N. Bubnov
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  2. S. A. Korobeinikova
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  3. G. V. Isagulyants
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  4. B. M. Mikhailov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2023–2028, September, 1970.

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Bubnov, Y.N., Korobeinikova, S.A., Isagulyants, G.V. et al. Organoboron compounds. Russ Chem Bull 19, 1902–1906 (1970). https://doi.org/10.1007/BF00849769

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  • DOI: https://doi.org/10.1007/BF00849769

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