Conclusions
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1.
The primary oxidation of terpinolene at the semicyclic double bond was confirmed, and it was shown that the dioxide has a trans-structure.
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2.
Terpinolene monoxide exists in solution in the form of a mixture of two half-chair forms; for the dioxide the boat conformation is stable.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1960–1963, September, 1970.
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Arbuzov, B.A., Arshinova, R.P., Vul'fson, S.G. et al. Dipole moments, molar Kerr constants, and structure of epoxy derivatives of terpinolene. Russ Chem Bull 19, 1844–1847 (1970). https://doi.org/10.1007/BF00849757
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DOI: https://doi.org/10.1007/BF00849757