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Synthesis of bis(organochlorosilyl) derivatives of aromatic hydrocarbons and of tristrichlorosilylbenzene

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the method of high-temperature condensation, a number of p-bis(organochlorosilyl) benzenes in which the two organochlorosilyl groups are different were synthesized. Tristrichlorosilylbenzene was also synthesized.

  2. 2.

    In the gas-phase reaction of chlorophenylsilanes with hydride chlorosilanes,an exchange of silyl group occurs.

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Literature cited

  1. E. A. Chernyshev and E. V. Vangnits, Zh. obshch. khimii,32, 24 (1962).

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Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    E. A. Chernyshev, E. V. Vangnits, V. M. Gel'perina & A. D. Petrov

Authors
  1. E. A. Chernyshev
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  2. E. V. Vangnits
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  3. V. M. Gel'perina
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  4. A. D. Petrov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seria Khimicheskaya, No. 10, pp. 1807–1814, October, 1964

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Chernyshev, E.A., Vangnits, E.V., Gel'perina, V.M. et al. Synthesis of bis(organochlorosilyl) derivatives of aromatic hydrocarbons and of tristrichlorosilylbenzene. Russ Chem Bull 13, 1714–1719 (1964). https://doi.org/10.1007/BF00849434

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  • DOI: https://doi.org/10.1007/BF00849434

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