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Kinetics of the symmetrization of organomercury salts Communication 8. Influence of polar factors on the rate of symmetrization of ethyl esters of α-bromomercuroarylacetic acids

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The influence of substituants on the reaction of bimolecular electrophilic substitution was studied for the example of symmetrization of organomercury salts of the type XC6H4CH(HgBr) COOC2H5 under the action of ammonia.

  2. 2.

    The substituents are arranged in the following series with respect to their accelerating influence: p-NO2 > m-Br > p-Br > 0-Br > m-CH3 > p-i-C3H7 > p-CH3 > o-CH3 > p-t-C4 H9.

  3. 3.

    The applicability of the Hammett equations to the series obtained was demonstrated.

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Literature cited

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Beletskaya, G. A. Artamkina & O. A. Reutov

Authors
  1. I. P. Beletskaya
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  2. G. A. Artamkina
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  3. O. A. Reutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seria Khimicheskaya, No. 10, pp. 1737–1742, October, 1964

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Beletskaya, I.P., Artamkina, G.A. & Reutov, O.A. Kinetics of the symmetrization of organomercury salts Communication 8. Influence of polar factors on the rate of symmetrization of ethyl esters of α-bromomercuroarylacetic acids. Russ Chem Bull 13, 1651–1655 (1964). https://doi.org/10.1007/BF00849423

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  • DOI: https://doi.org/10.1007/BF00849423

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