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Organoboron compounds

Communication 139. Reactions of organoboron thio esters with some bifunctional compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The reaction of dithioalkaneboronic esters with 1,6-hexanediamine leads to the formation of polymeric compounds, the composition of which depends on the proportions of the reactants.

  2. 2.

    Dibutyl dithiobenzeneboronate reacts with hydrazine with formation of hexahydro-3,6-diphenyl-1,2,4,5,3,6-tetrazadiborine.

  3. 3.

    With hydrazine, dibutyl dithioalkaneboronates give polymeric substances.

  4. 4.

    The reaction of dibutyl dithio-1-butane- and dithiobenzene-boronates with 4,4'-isopropylidenediphenol leads to the formation of cyclic esters.

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Literature cited

  1. Communications 134–136, Izv. AN SSSR. Ser. khim.,1964, 1874, 2247;1965, 68; 137-Dokl. AN SSSR,160, No. 3 (1965);138-Izv. AN SSSR. Ser. khim.,1965, 355.

  2. B. M. Mikhailov, T. K. Kozminskaya, N. S. Fedotov, and V. A. Dorokhov, Dokl. AN SSSR,127, 1023 (1959).

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Additional information

For preceding communication see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 439–442, March, 1965

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Mikhailov, B.M., Kozminskaya, T.K. Organoboron compounds. Russ Chem Bull 14, 424–427 (1965). https://doi.org/10.1007/BF00846596

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  • DOI: https://doi.org/10.1007/BF00846596

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