Summary
-
1.
The absolute values of the rate constant of the elementary reaction of oxygen atoms with acetylene were measured in the temperature interval 120–290°.
-
2.
A value of the activation energy of the rate constant of the reaction, equal to 3100 cal/mole was obtained, along with a value of the preexponential factor equal to 2.9·10−13 cm3·sec−1·molecule−1.
-
3.
The basic direction of the reaction of oxygen atoms with acetylene is the reaction proceeding with cleavage of the CΞC triple bond.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
P. Harteck and U. Kopsch, Z. phys. Chem.,B12, 327 (1931).
K. H. Geib, Z. Electrochim.47, 275 (1941).
L. I. Avramenko, R. V. Kolesnikova, and N. L. Kuznetsova, Izv. AN SSSR, Otd. Khim. N.,1962, 983.
L. I. Avramenko, R. V. Kolesnikova, and G. I. Savinova, Izv. AN SSSR, Otd. Khim. N.,1963, 36.
L. I. Avramenko, R. V. Kolesnikova, and N. L. Kuznetsova, Izv. AN SSSR, Otd. Khim. N.,1963, 620.
L. I. Avramenko, R. V. Kolesnikova, and G. I. Savinova, Izv. AN SSSR, Otd. Khim. N.,1963, 976.
L. I. Avramenko and R. V. Kolesnikova, Izv. AN SSSR. Otd. Khim. N.,1955, 386.
L. I. Avramenko, R. V. Kolesnikova, and L. M. Postnikov, Izv. AN SSSR Otd. Khim. N.,1958, 276.
L. I. Avramenko and R. V. Kolesnikova, Izv. AN SSSR. Otd. Khim. N.,1959, 1562.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 408–412, March, 1965
Rights and permissions
About this article
Cite this article
Avramenko, L.I., Kolesnikova, R.V. & Savinova, G.I. Mechanism and rate constant of the reaction of oxygen atoms with acetylene. Russ Chem Bull 14, 396–399 (1965). https://doi.org/10.1007/BF00846591
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00846591