Free-radical addition of low-molecular-weight alcohols to unsaturated compounds

  • G. I. Nikishin
  • V. D. Vorob'ev
Organic and Biological Chemistry

Summary

  1. 1.

    An investigation was made of the free-radical addition of low-molecular-weight alcohols to unsaturated compounds in a continuously operating laboratory apparatus working under a pressure of 10–30 atm.

     
  2. 2.

    1 ∶ 1 adducts of the alcohols with the unsaturated compounds were obtained in yields of 40–60%.

     

Keywords

Alcohol Adduct Laboratory Apparatus Unsaturated Compound 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    W. H. Urry, F. W. Stasey, E. S. Huyser, and O. O. Juveland, J. Amer. Chem. Soc.,76, 450 (1954).Google Scholar
  2. 2.
    G. I. Nikishin, V. D. Vorob'ev, and A. D. Petrov, Izv. AN SSSR, Otd. khim. n.,1961, 882.Google Scholar
  3. 3.
    G. I. Nikishin and V. D. Vorob'ev, Izv. AN SSSR, Otd. khim. n.,1962, 1847.Google Scholar
  4. 4.
    L. I. Antsus and A. D. Petrov, Izv. AN SSSR,Otd. khim. n.,1956, 1135.Google Scholar
  5. 5.
    C. Welling and G. Metzger, J. Amer. Chem. Soc.,81, 5365 (1959).Google Scholar
  6. 6.
    G. I. Nikishin, V. D. Vorob'ev, and A. D. Petrov, Dokl. AN SSSR,136, 360 (1961).Google Scholar
  7. 7.
    G. I. Nikishin and V. D. Vorob'ev, Izv. AN SSSR, Otd. khim. n.,1962, 892.Google Scholar
  8. 8.
    E. J. Boorman and R. P. Linstead, J. Chem. Soc.,1933, 578.Google Scholar
  9. 9.
    H. A. Schuette and P. P. T. San, J. Amer. Chem. Soc.,48, 3163 (1926).Google Scholar
  10. 10.
    R. L. Frank, R. Armstrony, J. Kwiatek, and H. A. Price, J. Amer. Chem. Soc.,70, 1379 (1948).Google Scholar
  11. 11.
    H. D. Zook and J. A. Knight, J. Amer. Chem. Soc.,76, 2304 (1954).Google Scholar
  12. 12.
    L. M. Ellis and E. E. Reid, J. Amer. Chem. Soc.,54, 1674 (1932).Google Scholar
  13. 13.
    L. E. Schniepp, H. H. Geller, and R. W. Von Korft, J. Amer. Chem. Soc.,69, 672 (1947).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1965

Authors and Affiliations

  • G. I. Nikishin
    • 1
  • V. D. Vorob'ev
    • 1
  1. 1.N. D. Zelinskii Institute of Organic Chemistry Academy of SciencesUSSR

Personalised recommendations