Summary
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1.
A technique has been developed which makes it possible to use a measurement of the force barrier between smooth solid metals as a function of potential to find the zero charge potential of the metals.
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2.
Curves have been obtained for the force barriers as a function of potential at various electrolyte concentrations. Measurements were made of the force barriers occurring when bringing together wires made of platinum, gold, and iron.
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3.
The zero charge points found are for platinum, 0.20 V, for gold, 0.05 V, for passive iron, 0.34 V, and for active iron −0.4 V.
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A. N. Frumkin, Uspekhi khimii4, 987 (1935); Izv. AN SSSR, Otd. khim. n. 3 (1940); Uspekhi khimii15, 385 (1946).
S. V. Karpachev and A. G. Stromberg, Zh. fiz. khimii7, 754 (1936);17, 1 (1943);68, 329 (1949); P. A. Rebinder and E. K. Benstrem, Zh. fiz. khimii19, 1 (1945); Dokl. AN SSSR68, 329 (1949); Ya. M. Kolotyrkin, and L. A. Medvedeva, Zh. fiz. khimii25, 1355 (1951).
A. N. Frumkin, A. Shlygin, and V. I. Medvedovskii, Izv. AN SSSR, Otd. khim. n. 773 (1936); A. V. Gorodetskaya and B. N. Kabanov, Zh. fiz. khimii4, 529 (1933); N. A. Balasheva, Dokl. AN SSSR103, 639 (1955); N. A. Balasheva and A. N. Frumkin, Dokl. AN SSSR20, 449 (1936).
T. N. Voropaeva, B. V. Deryagin, and B. N. Kabanov, Dokl. AN SSSR128, 981 (1959).
B. V. Deryagin and L. D. Landau, Zh. eksperim. i teor. fiz.15, 662 (1945);11, 802 (1941); Acta phys.-chim. USSR14, 633 (1941).
G. Guy, Paper in collection “Coagulation of Colloids” [in Russian] ONTI (1936).
G. Mazing, Z. Metallkunde,42, 361 (1951).
E. O. Avazyan, Dokl. AN SSSR100, 473 (1955).
M. A. Vorsina and A. N. Frumkin, Dokl. AN SSSR24, 918 (1939).
T. P. Kashcheeva, Dissertation, Moscow, Institute of Electrochemistry, Academy of Sciences USSR (1963).
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Voropaeva, T.N., Deryagin, B.V. & Kabanov, B.N. The crossed polarized metallic thread method for determining zero charge points. Russ Chem Bull 12, 234–238 (1963). https://doi.org/10.1007/BF00846388
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DOI: https://doi.org/10.1007/BF00846388