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Chemistry of acetals Communication 18. Rate of hydrolysis of certain mono- and diacetals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate constant of the first-order hydrolysis was determined for 29 different saturated and unsaturated mono- and diacetals.

  2. 2.

    The influence of electron-acceptor substituents on the rate of hydrolysis of the acetals was determined.

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Literature cited

  1. L. A. Yanovskaya and R. N. Stepanova, Izv. AN SSSR. Ser. Khim., 1416 (1965).

  2. L. A. Yanovskaya and V. F. Kucherov, Izv. AN SSSR. Otd. Khim. N., 667 (1962).

  3. L. A. Yanovskaya, B. A. Rudenko, V. F. Kucherov, R. N. Stepanova, and G. A. Kogan, Izv. AN SSSR. Otd. Khim. N., 2189(1962).

  4. M. M. Kreevoy and R. W. Taft, J. Amer. Chem. Soc.,77, 5590 (1955).

    Google Scholar 

  5. J. Mitchell, “Organic Analysis”, Vol. I,243, New York (1953).

  6. J. M. O'Gorman and H. J. Lucas, J. Amer. Chem. Soc.72, 5489 (1950).

    Google Scholar 

  7. M. M. Kreevoy and R. W. Taft, J. Amer. Chem. Soc.77, 3146 (1955).

    Google Scholar 

  8. I. N. Nazarov, S. M. Makin, and B. K. Kruptsov, Dokl. AN SSSR,117, 823 (1957); B. K. Kruptsov, Dissertation [in Russian], Moscow (1960).

    Google Scholar 

  9. M. Krausz, Ann. chim.12 4, 817 (1949).

    Google Scholar 

  10. A. N. Nesmeyanov, R. Kh. Freidlina, and L. I. Zakharkin, Dokl. AN SSSR,99, 781 (1955).

    Google Scholar 

  11. A. Wohl and F. Frank, Ber.35, 1904 (1902).

    Google Scholar 

  12. L. A. Yanovskaya, R. N. Stepanova, G. A. Kogan, and V. F. Kucherov, Izv. AN SSSR. Otd. Khim. N., 857 (1963).

  13. Syntheses of Organic Preparations, Collection [in Russian], Moscow,2 (1949), p. 65.

  14. Syntheses of Organic Preparations, Collection [in Russian], Moscow,3 (1952), p. 88.

  15. O. H. Johnson and J. R. Holum, J. Organ. Chem.23, 738 (1958).

    Google Scholar 

  16. Syntheses of Organic Preparations, Collection [in Russian], Moscow,4 (1953), p. 70.

  17. I. N. Nazarov, I. I. Nazarova, and I. V. Torgov, Dokl. AN SSSR,122, 82 (1958).

    Google Scholar 

  18. S. M. Makin and N. I. Telegin, Zh. Obshch. Khimii,32, 1104 (1962).

    Google Scholar 

  19. V. F. Kucherov, B. G. Kovalev, G. A. Kogan, and L. A. Yanovskaya, Dokl. AN SSSR,138, 1115 (1961).

    Google Scholar 

  20. H. O. L. Fisher and C. Taube, Ber.59, 853 (1926).

    Google Scholar 

  21. L. A. Yanovskaya, S. S. Yufit, and V. F. Kucherov, Izv. AN SSSR. Otd. Khim. N., 1946 (1959).

  22. N. A. Preobrazhenskii, I. A. Rubtsov, T. F. Dankova, and V. P. Pavlov, Zh. Obshch. Khimii,15, 952 (1945).

    Google Scholar 

  23. R. H. Hall and B. K. Howe, J. Chem. Soc, 2480 (1951).

  24. F. G. Fisher and K. Lowenberg, Ber.,66, 665 (1933).

    Google Scholar 

  25. L. A. Yanovskaya and V. F. Kucherov, Izv. AN SSSR. Otd. Khim. N., 2184 (1960).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    L. A. Yanovskaya & V. M. Belikov

Authors
  1. L. A. Yanovskaya
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  2. V. M. Belikov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1363–1369, August, 1965 Original article submitted June 25, 1963

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Yanovskaya, L.A., Belikov, V.M. Chemistry of acetals Communication 18. Rate of hydrolysis of certain mono- and diacetals. Russ Chem Bull 14, 1329–1334 (1965). https://doi.org/10.1007/BF00846187

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  • DOI: https://doi.org/10.1007/BF00846187

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