Conclusions
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1.
A theoretical analysis shows that under the conditions of Chromatographie separation, chemical reactions of various phase types acquire certain general characteristics-a shift of the equilibria, downward expansion of the temperature region, elimination of a number of side processes.
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2.
An experimental verification of the conclusions of the theory, with the catalytic dehydrogenation of cyclohexane and butane as an example, using pulsed and radiochromatography, confirmed the correctness of these conclusions.
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S. Z. Roginskii, M. I. Yanovskii, and G. A. Gaziev, Dokl. AN SSSR,140, 1125 (1961).
S. Z. Roginskii, M. I. Yanovskii, and G. A. Gaziev, Kinetika i Kataliz,3, No. 4,3, 539 (1962).
M. I. Yanovskii and G. A. Gaziev, Vestnik AN SSSR, No. 5, 1150 (1960).
G. V. Samsonov, E. A. Fokina, and M. I. Yanovskii, Dokl. AN SSSR,140, 863 (1961).
S. Z. Roginskii, E. I. Semenenko, and M. I. Yanovskii, Dokl. AN SSSR,153, No. 2 (1963).
C. O. Thomas and H. A. Smith, J. Phys. Chem.63, 427 (1959).
H. W. Joy and W. F. Libby, J. Chem. Phys.53, 1276 (1960).
C. T. Bishop, F. P. Cooper, and R. K. Murray, Canad. J. Chem.41, No. 9, 2245 (1963); J. J. Duffield, and L. B. Rogers, Analyt. Chem.34, No. 10, 1193 (1962).
F. M. Maggee, Industr. Ingng. Chem. Fundamentals,2, N 1 32 (1963).
S. Z. Roginskii and A. A. Rozental'. Dokl. AN SSSR,146, 155 (1962).
G. A. Gaziev, V. Yu. Filinovskii, and M. Ya. Yanovskii, Kinetika i Kataliz,44, 688 (1963).
S. Z. Roginskii and A. G. Rozental', Kinetika i Kataliz,5, 104 (1964).
V. S. Kruglyakova, V. G. Bereskin, M. A. Belikova, and V. E. Shiryaeva, Summaries of Reports at the Third All-Union Conference on Gas Chromatography [in Russian], Moscow (1964), p. 35.
S. Z. Roginskii and A. L. Rozental', All-Union Conference on Chemical Reactors [in Russian]. Novosibirsk,1, (1965), p. 100.
M. Matsen, I. W. Harding, and M. Magee, J. Phys. Chem.69, 522 (1965).
R. A. Zimin, S. Z. Roginskii, and M. I. Yanovskii, All-Union Conference on New Methods of Studying Catalysts and Reactions [in Russian]. Novosibirsk, 3 (1965), p. 279–289.
V. Yu. Filinovskii, G. A. Gaziev, and M. I. Yanovskii, Ibid. Novosibirsk,3 (1965), p. 313–323.
E. I. Semenenko, M. I. Yanovskii, and S. Z. Roginskii, Ibid., Novosibirsk (1965), p. 290–299.
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Report at the Session of the Department of General and Technical Chemistry of the Academy of Sciences USSR, November 22, 1963.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1321–1330, August, 1965 Original article submitted July 27, 1964
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Roginskii, S.Z. Chemical reactions in a chromatographic partitioning system. Russ Chem Bull 14, 1293–1300 (1965). https://doi.org/10.1007/BF00846181
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DOI: https://doi.org/10.1007/BF00846181