Skip to main content
Log in

Structure of vincanidine, an alkaloid from the roots of vinca erecta

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

The character of the ultraviolet and infrared spectral curves, the large angle of rotation, and the color indicate that the vincanidine molecule contains the 2-methyleneindoline chromophoric system conjugated with an aldehyde group, which is confirmed by the preparation of breakdown products of vincanidine: 3H-indole (II), indoline (III), and indole (IV) derivatives. Such a complex chromophoric system is characteristic for alkaloids of the vincanineakuammicine type.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. S. Yu. Yunusov and P. Kh. Yuldashev, Dokl. AN UzSSR No. 12, 24 (1952); Zh. obshch. khimii27, 2015 (1957).

    Google Scholar 

  2. K. Aghromurthy and R. Robinson, Tetrahedron,1, 172 (1957).

    Google Scholar 

  3. P. N. Edwards and G. F. Smith, J. Chem. Soc., 152 (1961).

  4. C. Djerassi, H. Budzikiewicz, J. M. Wilson, J. Gosset, J. Le Men, and M. M. Janot, Tetrahedron Letters, 235 (1962).

  5. M. Plat, J. Le Men, M. M. Janot, J. M. Wilson, H. Budzikiewicz, J. Durham, J. Nakagawa, and C. Djerassi, Tetrahedron Letters, 271 (1962).

  6. W. M. Philipsborn, H. Meyer, H. Schmid, and P. Karrer, Helv. Chim. Acta41, 1257 (1958).

    Google Scholar 

  7. P. Kh. Yuldashev and S. Yu. Yunusov, Dokl. AN UzSSR No. 3, 28 (1960).

    Google Scholar 

  8. G. F. Smith and J. F. Wrobel, J. Chem. Soc. 793 (1960).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 1992–1995, November 1965

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ubaev, K.U., Yuldashchev, P.K. & Yunusov, S.Y. Structure of vincanidine, an alkaloid from the roots of vinca erecta. Russ Chem Bull 14, 1958–1960 (1965). https://doi.org/10.1007/BF00845889

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00845889

Keywords

Navigation