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Chemiluminescence in inhibited oxidation reactions, and the activity of inhibitors Communication 2. Measuring the activity of inhibitors by chemiluminescence methods

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It is shown that it is possible to use chemiluminescence methods for measuring the activity of inhibitors and verifying the mechanism by which they act.

  2. 2.

    Measurements are made of the relative values of the rate constants for reactions between peroxide radicals and various inhibitors (phenols and amines).

  3. 3.

    An explanation is given for the effect which the nature of the substance undergoing oxidation has on the chemiluminescence kinetics and on the relations between the luminescence intensity and the inhibited concentration.

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Literature cited

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Authors and Affiliations

  1. Institute ofChemical Physics, Academy of Sciences, USSR

    O. N. Karpukhin, V. Ya. Shlyapintokh & N. V. Zolotova

Authors
  1. O. N. Karpukhin
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  2. V. Ya. Shlyapintokh
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  3. N. V. Zolotova
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Additional information

This paper is published on the basis of a resolution adopted by a meeting of the principal editors of the journals of the Academy of Sciences, USSR, held July 12, 1962, as the dissertation work of O. N. Karpukhin.

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Karpukhin, O.N., Shlyapintokh, V.Y. & Zolotova, N.V. Chemiluminescence in inhibited oxidation reactions, and the activity of inhibitors Communication 2. Measuring the activity of inhibitors by chemiluminescence methods. Russ Chem Bull 12, 1581–1585 (1963). https://doi.org/10.1007/BF00845782

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  • DOI: https://doi.org/10.1007/BF00845782

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