Summary
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1.
By reduction of 2-nitroperfluoropropane, we have obtained and characterized hexafluoroisopropylamine.
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2.
By nitrosation of hexafluoroisopropylamine, we have obtained 2-diazoperfluoropropane (bistrifluoromethyldiazomethane).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 926–928, May, 1965 Original article submitted August 28, 1964
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Mochalina, E.P., Dyatkin, B.L. The synthesis of 2-diazoperfluoropropane (bistrifluoromethyldiazomethane). Russ Chem Bull 14, 899–901 (1965). https://doi.org/10.1007/BF00845719
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DOI: https://doi.org/10.1007/BF00845719