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Preparation of α-olefins from boron trialkyls

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the action of aromatic aldehydes on boron trialkyls (RR'CH-CH2)3B we obtained pure α-olefins RR'C=CH2.

  2. 2.

    In the case of 1-methylcyclohexene and 1-methylcyclopentene we showed the possibility of converting the methylcyclene into the corresponding methylenecyclane.

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Literature cited

  1. H. Meerwein, G. Hinz, H. Majert, and H. Sönke, J. prakt. Chem.,147, 226 (1936).

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  2. H. C. Brown, Hydroboration, New York (1962).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    B. M. Mikhailov, V. G. Kiselev & Yu. N. Bubnov

Authors
  1. B. M. Mikhailov
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  2. V. G. Kiselev
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  3. Yu. N. Bubnov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 898–900, May, 1965 Original article submitted July 22, 1964

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Mikhailov, B.M., Kiselev, V.G. & Bubnov, Y.N. Preparation of α-olefins from boron trialkyls. Russ Chem Bull 14, 865–867 (1965). https://doi.org/10.1007/BF00845705

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  • DOI: https://doi.org/10.1007/BF00845705

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