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The infrared spectra of aroylmethylene triphenylphosphoranes and their salts

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    We have measured the integral intensities of carbonyl absorption in aroylmethylene triphenylphosphoranes and their salts. The observed facts are discussed from the point of view of electron donor and electron acceptorproperties of the phosphorus atom and the aromatic nuclei of the aroyl groups.

  2. 2.

    We have suggested a relationship for the absorption bands in the region 1317–1390 cm−1 for aryl and 1389–1412 cm−1 for aroylmethylene triphenylphosphoranes to oscillation of the P=C bond.

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Authors and Affiliations

  1. Institute of the Chemistry of National Compounds, Academy of Sciences, USSR

    L. B. Senyavina, Yu. N. Sheinker, V. N. Zheltova, A. V. Dombrovskii & M. N. Shevchuk

Authors
  1. L. B. Senyavina
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  2. Yu. N. Sheinker
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  3. V. N. Zheltova
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  4. A. V. Dombrovskii
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  5. M. N. Shevchuk
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 895–898, May, 1965 Original article submitted July 20, 1964

The present paper is the spectroscopic portion of the work carried out by the authors with M. I. Kabachnik, T. A. Mastryukova, and T. A. Melent'eva.

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Senyavina, L.B., Sheinker, Y.N., Zheltova, V.N. et al. The infrared spectra of aroylmethylene triphenylphosphoranes and their salts. Russ Chem Bull 14, 862–864 (1965). https://doi.org/10.1007/BF00845704

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  • DOI: https://doi.org/10.1007/BF00845704

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