Summary
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1.
From the roots ofClematis manshurica Rupr. a triterpene saponin-a glycoside of oleanolic acid called clematoside C-was isolated.
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2.
Clematoside C is a decaoside of oleanolic acid and contains residues of glucose, arabinose, xylose, and rhamnose in the proportions 5∶1∶1∶3.
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3.
Clematoside C is an O-acyl glycoside in which a carbohydrate chain consisting of glucose and rhamnose residues is attached at the hindered carboxy group. At the 3-position of the genin a carbohydrate chain containing glucose, arabinose, xylose, and rhamnose residues is attached.
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N. K. Kochetkov and A. Ya. Khorlin, Dokl. AN SSSR,150, 1289 (1963).
B. Rutovski, J. Vinogradova, and A. Kondratskii, Chem. Zentr.,1, 1304 (1926).
W. Herz, A. L. Pates, and J. C. Madsen, Science,114, 206 (1951); Chem. Abstrs.,46, 580c (1952).
Kum Haw and Don Ko, Repts. Natl. Chem. Lab. (Korea),3, 57 (1959); Chem. Abstrs.,54, 11171h (1960).
E. Wagner, Seifensieder-Ztg.,68, 35 (1941); Chem. Abstrs.,35, 30333 (1941).
Masao Fukuda and Masatake Kasai, J. Chem. Soc., Japan,55, 1252 (1934); Chem. Abstrs., 29, 43659 (1935).
K. Ishiwadari and K. Nakano, Chem. Abstrs.,45, 3562 (1951).
A. Ya. Khorlin, L. V. Bakinovskii, A. E. Vas'kovskii, A. G. Ven'yaminova, and Yu. S. Ovodov, Izv. AN SSSR. Sci. khim.,1963, 2008.
N. K. Kochetkov, A. Ya. Khorlin, and Yu. S. Ovodov, Izv. AN SSSR. Ser. khim.,1964, 1436.
H. W. Wood, Jr., R. Allerton, H. W. Diene, and H. G. Fletcher, J. Organ. Chem.,20, 857 (1955).
N. K. Kochetkov, A. Ya. Khorlin, L. A. Vorotnikova, and V. E. Vas'kovskii, Izv. AN SSSR Otd. khim. n.1960, 568.
S. B. Misra and V. K. MohanRaoJ. Sci. Ind. Res.BC19, No. 7, 173 (1960).
A. Ya. Khorlin, Yu. S. Ovodov, and P. G. Ovodova, Izv. AN SSSR, Ser. khim.,1963, 1521.
A. Ya. Khorlin and V. I. Ivanova, Izv. AN SSSR, Ser. khim.,1965, 307.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 811–818, May, 1965 Original article submitted May 24, 1963
For Communication 13 in this series, “Triterpenoid Saponins,” see [13]; for Communication 14 see [14].
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Khorlin, A.Y., Chirva, V.Y. & Kochetkov, N.K. Triterpenoid saponins Communication 15. Clematoside C-A triterpenoid oligoside from the roots of the manchurian clematis (Clematis manshurica RUPR.). Russ Chem Bull 14, 790–795 (1965). https://doi.org/10.1007/BF00845689
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DOI: https://doi.org/10.1007/BF00845689