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Study of tautomerism and geometrical isomerism in derivatives of carbonyl compounds containing nitrogen

Communication 8. Polarographic study of tautomerism in phenylhydrazoxes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Using the polarographic method it has been shown that in methanol-water solutions of phenylhydrazones of several aldehydes and ketones the following three tautomeric structures are formed, directly or indirectly: the enhydrazinic, the hydrazonic, and the azo-structure.

  2. 2.

    The polar effect of substituents on the polarographic reduction of the tautomeric forms of the compounds examined has been characterized by means of Taft-Hammett's equation.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Chemical Institute, Academy of Sciences, USSR

    Yu. P. Kitaev & T. V. Troepol'skaya

Authors
  1. Yu. P. Kitaev
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  2. T. V. Troepol'skaya
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Kitaev, Y.P., Troepol'skaya, T.V. Study of tautomerism and geometrical isomerism in derivatives of carbonyl compounds containing nitrogen. Russ Chem Bull 12, 408–417 (1963). https://doi.org/10.1007/BF00844391

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  • DOI: https://doi.org/10.1007/BF00844391

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