Summary
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1.
A new method is proposed for the preparation of bisalkylxanthogen trisulfides by heating the corresponding disulfides with sulfur in a boiling water bath.
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2.
Under these conditions dialkyl disulfides do not react with sulfur.
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3.
Nine bisalkylxanthogen trisulfides and eight bisalkylxanthogen disulfides were synthesized; of these,bisoctylxanthogen and bisnonylxanthogen disulfides have not been described previously.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12 p. 2175–2182, December, 1964
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Bokarev, K.S., Kraft, V.A. & Kapelyushnikova, L.M. Synthesis of bisalkylxanthogen trisulfides [O,O-dialkyl trithiobis(thioformates)]. Russ Chem Bull 13, 2074–2080 (1964). https://doi.org/10.1007/BF00844218
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DOI: https://doi.org/10.1007/BF00844218