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Oxidative transformations of diisobornyl disulfide

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Abstract

Oxidation of diisobornyl disulfide with m-chloroperoxybenzoic acid, lead tetracetate, and chlorine dioxide was studied. Depending on the reaction conditions, the following products with the increasing oxidation number of the sulfur atom were obtained: diisobornyl trisulfide, isobornyl isobornanethiosulfinate, isobornanesulfinyl chloride, isobornanesulfinic, isobornanesulfonic acid and their esters.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Scientific Center, Ural Branch of the Russian Academy of Sciences, 48 ul. Pervomaiskaya, 167982, Syktyvkar, Russian Federation

    E. S. Izmest´ev, O. M. Lezina, O. N. Grebyonkina, S. A. Patov, S. A. Rubtsova & A. V. Kutchin

Authors
  1. E. S. Izmest´ev
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  2. O. M. Lezina
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  3. O. N. Grebyonkina
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  4. S. A. Patov
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  5. S. A. Rubtsova
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  6. A. V. Kutchin
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Corresponding author

Correspondence to E. S. Izmest´ev.

Additional information

Based on the materials of the VIII All-Russian Conference "Chemistry and Technology of Plant Substances" (October, 7—10, 2013, Kaliningrad).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2067—2073, September, 2014.

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Izmest´ev, E.S., Lezina, O.M., Grebyonkina, O.N. et al. Oxidative transformations of diisobornyl disulfide. Russ Chem Bull 63, 2067–2073 (2014). https://doi.org/10.1007/s11172-014-0702-8

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  • DOI: https://doi.org/10.1007/s11172-014-0702-8

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